Periodic Classification of Elements
Multiple Choice Questions
1. Upto which element, the Law of Octaves was found to be applicable
(a) Oxygen
(b) Calcium
(c) Cobalt
(d) Potassium
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Answer
(b) Calcium
Explanation
Newland’s law of octaves was applicable to the elements with atomic mass up to 40 da which comes up to Calcium. After calcium every eighth element possess properties similar to that of the first.
(a) increasing atomic number
(b) decreasing atomic number
(c) increasing atomic masses
(d) decreasing atomic masses
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Answer
(c) increasing atomic masses
Explanation
(a) Germanium
(b) Chlorine
(c) Oxygen
(d) Silicon
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Answer
(a) Germanium
Explanation
Mendeleev name unnamed elements as EKA- Boron EKA- Aluminium and EKA Silicon which were later replaced as Scandium, Gallium, and germanium respectively.
following statement (s)
about the Modern Periodic Table are incorrect
(i) The elements in the Modern Periodic Table are arranged on the basis of their decreasing atomic number
(ii) The elements in the Modern Periodic Table are arranged on the basis of their increasing atomic masses
(iii) Isotopes are placed in adjoining group (s) in the Periodic Table
(iv) The elements in the Modern Periodic Table are arranged on the basis of their increasing atomic number
(a) (i) only
(b) (i), (ii) and (iii)
(c) (i), (ii) and (iv)
(d) (iv) only
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Answer
(b) (i), (ii) and (iii)
Explanation
Elements in the Modern Periodic Table are arranged on the basis of their increasing atomic number hence option i) is wrong . In modern periodic table atomic mass is not a criteria hence option ii) is wrong. Isotopes are given the same position in periodic table hence option iii) is wrong.
(a) It has 18 horizontal rows known as Periods
(b) It has 7 vertical columns known as Periods
(c) It has 18 vertical columns known as Groups
(d) It has 7 horizontal rows known as Groups
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Answer
(c) It has 18 vertical columns known as Groups
Explanation
Modern periodic table have 18 groups and 7 periods. Columns are called groups and rows are called priods.
(a) A, B, C
(b) B, C, D
(c) A, D, E
(d) B, D, E
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Answer
(b) B, C, D
Explanation
Element with atomic number belong to first period and element B, C and D belongs to second period.
(a) A and
(b) B and D
(c) A and C
(d) D and E
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Answer
(c) A and C
Explanation
(a) Group 8
(b) Group 2
(c) Group 18
(d) Group 10
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Answer
Ans is (c) Group 18
Explanation
Group 18 has its outermost shells completely filled hence element with electronic configuration belongs to group 18.
(a) group 1
(b) group 14
(c) group 15
(d) group 16
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Answer
b) group 14
Explanation
Carbon is an essential constituent of all organic compounds which belongs to group 14.
(a) K shell
(b) L shell
(c) M shell
(d)
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Answer
(b) L shell
Explanation
In period 18 there are two shells
(a)
(b) Al
(c)
(d)
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Answer
(d)
Explanation
Electronic configuration of
(a) O, F, N
(b) N, F, O
(c) O, N, F
(d) F, O, N
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Answer
(d) F, O, N
Explanation
Atomic radius increase as move from left to right across a period. (N7),
(a)
(b)
(c)
(d)
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Answer
(c)
Explanation
(a)
(b)
(c)
(d)
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Answer
(b) Na
Explanation
Na and
(a)
(b)
(c)
(d)
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Answer
Sodium has 1, magnesium has 2 and Aluminium has 3 electron in its outermost shell whereas Fluorine has 7 electron in its outermost shell hence Fluorine does not lose electron easily.
(i) Isotopes of an element have same atomic masses
(ii) Isotopes of an element have same atomic number
(iii) Isotopes of an element show same physical properties
(iv) Isotopes of an element show same chemical properties (a) (i), (iii) and (iv)
(b) (ii), (iii) and (iv)
(c) (ii) and (iii)
(d) (ii) and (iv)
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Answer
(d) (ii) and (iv)
Explanation
Elements with same atomic number but different atomic masses are known as isotopes. Isotopes same chemical properties but differ in their physical properties.
(b)
(c)
(d)
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Answer
(b)
Explanation
Na has 1, magnesium has 2 , aluminium has 3 and Chlorine has 7 electrons in its valence shells. Hence Sodium shows maximum metallic characters followed by Magnessium, aluminium and chlorine shows non-metallic properties.
(b)
(c)
(d) F
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Answer
(a)
(b)
(c)
(d)
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Answer
(c)
(a) metals
(b) non-metals
(c) metalloids
(d) metal, non-metal and metalloid respectively
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(c) metalloids
(a) An element with atomic number 7
(b) An element with atomic number 3
(c) An element with atomic number 12
(d) An element with atomic number 19
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Answer
(a) An element with atomic number 7
Explanation
Element with atomic number 7 has electron configuration 2,5 which means it can gain 3 electrons and is a electronegative element. It should be a non-metal and non-metals will form acidic oxide.
(a) Metal
(b) Metalloid
(c) Non-metal
(d) Left-hand side element
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Answer
(b) Metalloid
Explanation
Element with atomic no. 14 is Silicon and is a metalloid. It forms acidic oxide , thus behaving as a nonmetal and also forms covalent halide, thus acting as a metal.

Options
(a) (i) and (ii)
(b) (ii) and (iii)
(c) (iii) and (iv)
(d) (i) and (iv)
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Answer
(b) (ii) and (iii)
Explanation
Atomic radius is the distance between the nucleus and outermost orbital is shown clearly in images ii) and iii) where as in image i) and iv) it is not depicted.
(a) Atomic radius
(b) Metallic character
(c) Valence
(d) Number of shells in an element
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Answer
(c) Valence
Explanation
Valency remain same in a group.
(a) increases
(b) decreases
(c) does not change appreciably
(d) first decreases and then increases
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Answer
(b) decreases
Explanation
Atomic radius decreases when we move from left to right in a periods hence the size of the atom also decreases.
(a) Be Mg Ca
(b) Na Li K
(c)
(d)
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Answer
(a) Be Mg Ca
Explanation
Metallic character increase as we move down the group. In the elements that belong to same group Berrylium is at the top and Calcium is at the bottom.
Short Answer Questions
27. The three elements
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Answer
Such an arrangement of elements are called Triads. Ex: Lithium Sodium and Potassium make a triad. Their atomic masses are 6.9, 23.0 and 39.0 respectively. An average mass of
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Answer
a)
b) Given set represent Mendeleev’s law of periodicity.
(a)
(b) Be, Mg, Ca
Atomic mass of
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Answer
Though atomic mass of Silicon is the average of atomic masses of Sodium and Chlorine they do not have similar properties hence they cannot be classified as Dobereiner’s triad
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Answer
In Mendeleev ’s Periodic Table there are instances where elements with higher atomic mass is placed before the element with lower atomic mass. This was done to ensure that elements with similar properties were included in the same group. Hence Cobalt was placed before Nickel despite of higher atomic number of Cobalt than Nickel.
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Answer
Hydrogen occupies a unique position in Modern Periodic Table because of the following reasons.
1 Hydrogen and alkali metals have similar outer electronic configuration as both have one electron in their outermost shell.
2 Properties of Hydrogen are similar to properties of Halgens as electronic configurations of halogens and Hydrogen are same.
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Chlorides of Eka-silicon:
Chlorides of Eka-Aluminium:
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Answer
A Belongs to Group 13, A Belongs to Group 14 and C Belongs to Group 2. Valency of A is3, B is 4 and C is 2.
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Answer
If an element
(a)
(b)
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Answer
From electron arrangement
Since
(a) Li, Be, F, N
(b) Cl, At, Br I
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Answer
Given elements are in the same group and are arranged from left to right. So Increasing order of their atomic radiiis
a)
b)
(a) 2, 8, 2
(b) 2, 8, 1
(c) 2, 8, 7
(d) 2, 1
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Answer
a) Magnesium
b) Sodium
c) Chlorine
d) Lithium
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Answer
Element A is K (Potassium).
The electronic configuration of element A (atomic number 19) would be 2, 8, 8, 1. As it has only one valence electron therefore it must be a metal. Thus it is potassium.
Element B is Cl (Chlorine).
The electronic configuration of element B (atomic number 17) would be 2, 8, 7. As it has 7 valence electrons therefore it must be a non-metal. Thus it is chlorine.
A metal and a non-metal usually combine with an ionic bond. Metals have tendency to lose electrons and form cations whereas non-metals can accept electrons to form anions.
AB

Potassium and chlorine will combine with an ionic bond to form potassium chloride (
The electron dot structure of

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Answer
(a) An element which is a soft and reactive metal
(b) The metal which is an important constituent of limestone
(c) The metal which exists in liquid state at room temperature
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Answer
a) Sodium
b) Calcium
c) Mercury
(a) A soft metal stored under kerosene
(b) An element with variable (more than one) valency stored under water.
(c) An element which is tetravalent and forms the basis of organic chemistry
(d) An element which is an inert gas with atomic number 2
(e) An element whose thin oxide layer is used to make other elements corrosion resistant by the process of " anodising"
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Answer
a) Sodium Group 1 Period 3
b) Phosphorus Group 15 Period 3
c) Carbon Group 14 Period 2
d) Helium Group 18 Period 1
e) Aluminium Group 13 Period 3
Long Answer Questions
42. An element is placed in 2nd Group and 3rd Period of the Periodic Table, burns in presence of oxygen to form a basic oxide.
(a) Identify the element
(b) Write the electronic configuration
(c) Write the balanced equation when it burns in the presence of air
(d) Write a balanced equation when this oxide is dissolved in water
(e) Draw the electron dot structure for the formation of this oxide
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Answer
a) Element is Magnessium
b) Electronic Configuration-2,8,2
c)
d)

(a) Where in the periodic table are elements
(b) Classify
(c) What will be the nature of oxide of element Y? Identify the nature of bonding in the compound formed
(d) Draw the electron dot structure of the divalent halide
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Answer
a)
c) Y Oxide will be basic in nature. Compound formed by ionic bond. d)

Electron dot structure for calcium chloride

(a) Identify the elements
(b) Identify the Group number of these elements in the Periodic Table
(c) Identify the Periods of these elements in the Periodic Table
(d) What would be the electronic configuration for each of these elements?
(e) Determine the valency of these elements
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Answer
a) Elements are Neon (10) Calcium (20) Nitrogen (7) Silicon (14)
b) Neon belongs to group 18, Calcium belongs to group 2, Nitrogen belongs to group 7 and Silicon belongs to group 14.
c) Nitrogen and Neon belong to period 2. Calcium and silicon belongs to Period 3.
d) Electronic Configurations
Neon-2,8
Calcium-2,8,8,2
Nitogen-2,5
Silicon-2,8,4
e) Valency
Neon-0
Calcium-2
Nitogen-3
Silicon-4
Fig. 5.1
Across:
(1) An element with atomic number 12.
(3) Metal used in making cans and member of Group 14.
(4) A lustrous non-metal which has 7 electrons in its outermost shell.
Down:
(2) Highly reactive and soft metal which imparts yellow colour when subjected to flame and is kept in kerosene.
(5) The first element of second Period
(6) An element which is used in making fluorescent bulbs and is second member of Group 18 in the Modern Periodic Table
(7) A radioactive element which is the last member of halogen family.
(8) Metal which is an important constituent of steel and forms rust when exposed to moist air.
(9) The first metalloid in Modern Periodic Table whose fibres are used in making bullet-proof vests
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Answer
Across
- Magnesium
- Tin
- Iodine
Down
- Sodium
- Lithium
- Neon
- Astatine
- Iron
- Boron
(b) Arrange them in the order of their group also.

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Answer
a) H, He, Li, Be, B, C, N, O, F, Ne, Mg, Al Si,P, S, Cl, Ar, K, Ca
b)
Group 1:H, Li, Na, K
Group 2: Be, Mg,Ca
Group 13: B. Al
Group 14: C, Si
Group 15: N. P
Group 16: 0, S
Group 17: F. U
Group 18: He, Ne, Ar
(a) Name the elements which have taken the place of these elements
(b) Mention the group and the period of these elements in the Modern Periodic Table.
(c) Classify these elements as metals, non-metals or metalloids
(d) How many valence electrons are present in each one of them?
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Answer
a) Eka-Silicon was replaced by germanium, Eka-aluminium was replaced by Gallium
b) Germanium-Group 14 Period 5
Gallium-Group 13 Period 5
c) Germanium is a metalloid and Gallium is a metal.
d) Germanium has 4 electron, Gallium has 3 valence electrons
(b) Electronegativity of the element decreases down the group and increases across the period
(c) Atomic size increases down the group and decreases across a period (left to right)
(d) Metallic character increases down the group and decreases across a period.
On the basis of the above trends of the Periodic Table, answer the following about the elements with atomic numbers 3 to 9 .
(a) Name the most electropositive element among them
(b) Name the most electronegative element
(c) Name the element with smallest atomic size
(d) Name the element which is a metalloid
(e) Name the element which shows maximum valency.
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Answer
(a)Electropositive nature of the element(s) increases down the group and decreases across the period.
(b) Electronegativity of the element decreases down the group and increases across the period
(c) Atomic size increases down the group and decreases across a period (left to right)
(d) Metallic character increases down the group and decreases across a period.
a) Lithium is the most electropositive element .
b) Fluorine is the most electronegative element
c) ) Fluorine is the element with smallest atomic size among the given elements
c) Boron
d) Carbon is the element which shows maximum valency.
(a) Identify the element
(b) Write the electronic configuration of
(c) Write the balanced chemical equation for the thermal decomposition of ferrous sulphate crystals?
(d) What would be the nature (acidic/ basic) of oxides formed?
(e) Locate the position of the element in the Modern Periodic Table
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Answer
a) Element
b) 2,8,6
c)
d) Sulphur oxides are acidic in nature
e) Group 16 Period 3
(a) Identify the element
(b) Draw the electron dot structure of the diatomic molecule of
(c) Draw the electron dot structure for ammonia and what type of bond is formed in it?
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Answer
(a) Answer is Nitrogen and it has 5 electrons in its outermost shell.
(b)

Triple covalent bonds
(c) Ammonia forms covalent bonding

3 single covalent bond

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Answer
Inert gases could be placed in Mendeleev’s Periodic Table without disturbing the original order.
Before Mendeleev Noble gases; like Helium. Neon and Argon had been mentioned by various scientists. But these gases could be grouped together as noble gases much later than Mendeleev’s discovery.
Mendeleev used 63 elements till his periodic table because these were the only known elements till his time. However, he was bold enough to leave gaps in his periodic table. He had predicted that that more elements would be discovered in times to come.
Mendeleev’s Periodic Table was the first comprehensive attempt to classify elements on the basis of their chemical properties. This is the main reason that new elements could be easily placed in Mendeleev’s Periodic Table without disturbing the original order.
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Answer
During Mendeleev’s time, only 63 elements were known. Mendeleev examined the correlation between chemical properties and Atomic manes of elements. For this, he concentrated on compounds which were formed by the elements with hydrogen and oxygen. He selected hydrogen and oxygen, because these elements make compound with most of the other elements.
Mendeleev made 63 cards and wrote the name of an element on each card: along with the chemical properties of a particular element. Then, he pinned those cards on a wall. He could observe that most of the elements could be arranged in periodic table in increasing order of their atomic masses. That is how Mendeleev arrived at “Periodic law”. Mendeleev’s Periodic Law states that properties of elements are periodic function of their atomic masses.