Haloalkanes And Haloarenes Question 13

Question 13 - 2024 (31 Jan Shift 2)

The correct order of reactivity in electrophilic substitution reaction of the following compounds is :

(1) $B>C>A>D$

(2) $D>C>B>A$

(3) $A>B>C>D$

(4) $B>A>C>D$

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Answer (4)

Solution

Formula: Electrophilic Substitution Reaction

$-CH _3$ shows $+M$ and $+I$.

$-Cl$ shows $+M$ and $-I$ but inductive effect dominates.

$-NO _2$ shows $-M$ and $-I$.

Electrophilic substitution $\alpha \frac{1}{-M \text { and -I }}$

$\alpha+M$ and $+I$

Hence, order is $B>A>C>D$.