Aliphatic Compounds Containing Nitrogen - Result Question 24

####25. $p$-chloroaniline and anilinium hydrochloride can be distinguished by

$(1998,2 M)$

(a) Sandmeyer reaction

(b) $NaHCO _3$

(c) $AgNO _3$

(d) Carbylamine test

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Answer:

Correct Answer: 25. (c)

Solution:

  1. $C _6 H _5 \stackrel{+}{N} H _3 Cl^{-}+AgNO _3 \longrightarrow C _6 H _5 \stackrel{+}{N} H _3 NO _3^{-}+AgCl(s) \downarrow$ anilinium hydrochloride

No such precipitate of $AgCl(s)$ would be formed with $p$-chloroaniline.



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