Aliphatic Compounds Containing Nitrogen - Result Question 24

####25. p-chloroaniline and anilinium hydrochloride can be distinguished by

(1998,2M)

(a) Sandmeyer reaction

(b) NaHCO3

(c) AgNO3

(d) Carbylamine test

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Answer:

Correct Answer: 25. (c)

Solution:

  1. C6H5N+H3Cl+AgNO3C6H5N+H3NO3+AgCl(s) anilinium hydrochloride

No such precipitate of AgCl(s) would be formed with p-chloroaniline.



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