Alcohols and Ethers - Result Question 8

####11. The major product formed in the following reaction is

(2018 Main) (a)

(c)

(b)

(d)

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Answer:

Correct Answer: 11. (d)

Solution:

  1. Key idea The reaction given is a nucleophilic substitution reaction in which cleavage at CO bond is visible. The product formation can be visualised with the help of following analysis.

If any one properly visualise the fact written with figure above, than a conclusion can be made that CO bonds marked (a) and (b) in the figure will undergo heterolysis during the reaction.

The reaction can be represented as

Mechanism

Step I The reaction begins with the attack of H+of HI on oxygen to form oxonium ion as

Step II This oxonium ion undergoes lysis and addition of Ito form two products as

Step III Similar pathway is followed at the other oxygen atom, which can be visualised as

Note Mechanism of a reaction is always a logical sequencing of events which may occur simultaneously as well.



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