Atomic Models
ATOMIC MODELS
Dalton’s Atomic Theory:
- Matter is made up of tiny, indivisible particles called atoms.
- All atoms of a given element are identical.
- Atoms combine in simple, whole-number ratios to form compounds.
Thomson’s Model of Atom:
- Also known as the “plum pudding model,” shows that atoms are composed of positively charged material with electrons embedded within it.
- Electrons are spread throughout the atom, like plums in a pudding.
Rutherford’s Model of Atom:
- Based on the gold foil experiment, where a beam of alpha particles was fired at a thin sheet of gold foil.
- Results showed that most alpha particles passed through the foil, but a small number was deflected at large angles, indicating the presence of a small, dense, positively charged nucleus.
Bohr’s Model of Atom:
- Proposed that electrons move in fixed circular orbits around the nucleus.
- Each orbit has a specific energy, and electrons can move from one orbit to another by absorbing or releasing energy.
Quantum Mechanical Model of Atom:
- Electrons do not move in fixed circular orbits, but rather in three-dimensional orbitals around the nucleus.
- Orbitals are defined by the quantum numbers that describe the electron’s energy, shape, and orientation.
Dual Nature of Matter:
- Electrons and photons have both particle and wave properties.
- Louis de Broglie proposed the wave-particle duality of matter, which states that all matter has both wave and particle characteristics.
Heisenberg’s Uncertainty Principle:
- States that it is impossible to simultaneously know both the exact momentum and position of a subatomic particle.
- The more precisely one property is known, the less precisely the other can be known.
Quantum Numbers:
- Describe the properties of electrons in an atom.
- Include the principal quantum number (n), angular momentum quantum number (l), magnetic quantum number (ml), and spin quantum number (ms).
Electronic Configuration:
- The arrangement of electrons in orbitals within an atom.
- Determined by the Aufbau principle, Pauli’s exclusion principle, and Hund’s rule.
Aufbau Principle:
- States that electrons fill orbitals in order of increasing energy.
- Lower energy orbitals are filled before higher energy orbitals.
Pauli’s Exclusion Principle:
- States that no two electrons in an atom can have the same set of four quantum numbers.
- Each electron must be unique.
Hund’s Rule:
- States that electrons in orbitals of the same energy tend to occupy different orbitals with the same spin before pairing up.
- This maximizes the total spin of the atom.