dual-nature-of-radiation-and-matter Question 11

Question: Q. 3. If light of wavelength $412.5 \mathrm{~nm}$ is incident on each of the metals given below, which ones will show photoelectric emission and why?

Metal Work Function (eV)
$\mathrm{Na}$ 1.92
$\mathrm{K}$ 2.15
$\mathrm{Ca}$ 3.20
$\mathrm{Mo}$ 4.17

R [OD 2018]

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Solution:

Ans. Calculating the energy of the incident photon 1 Identifying the metals Reason

The energy of a photon of incident radiation is given by

$$ \begin{align*} E & =\frac{h c}{\lambda} \ E & =\frac{6.63 \times 10^{-34} \times 3 \times 10^{8}}{\left(412.5 \times 10^{-9}\right) \times\left(1.6 \times 10^{-19}\right)} \mathrm{eV} \ & =3.01 \mathrm{eV} \end{align*} $$

Hence, only $\mathrm{Na}$ and $\mathrm{K}$ will show photoelectric emission.

[Note: Award this $1 / 2$ mark even if the student writes the name of only one of these metals]

Reason : The energy of the incident photon is more than the work function of only these two metals. $1 / 2$

[CBSE Marking Scheme 2018]

Detailed Answer :

Given, $\lambda=412.5 \mathrm{~nm}=4125 \AA$

$\therefore$ Energy of light, $E_{\lambda}=\frac{12375}{4125} \mathrm{eV}$

$$ E_{\lambda}=3.0 \mathrm{eV} $$

Now for photoelectric emission, we should have energy of incident light higher than the work function of metal. Since work function of $\mathrm{Na}$ and $\mathrm{K}$ is less than $E_{\lambda}$, so these metals $\mathrm{Na}$ and $\mathrm{K}$ show photo electric emission.

But for $\mathrm{Ca}$ and Mo, work function is more than $E_{\lambda^{\prime}}$, so these metals $\mathrm{Ca}$ and Mo, do not show photoelectric emission.

Answering Tips

  • Before comparing the work function energy the incident radiation photon energy should be converted in e.V.


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