Redox Reactions And Electrochemistry Ques 715

Question: Acidulated water is electrolysed by 1 A current for 16 min and 5s using inert electrodes, The volume of gases liberated at STP will be

Options:

A) 22.4 mL

B) 112 mL

C) 168 mL

D) 336 mL

Show Answer

Answer:

Correct Answer: C

Solution:

[c] At cathode H2O+2e,,H2+2OH At Anode H2O,12,O2+2H+2e i.e., on passing 2 mol of current, 1 mol H2(g) and 12,molO2(g) is liberated at cathode and anode respectively. From Q=it =,1×(16×60+5)=965C the amount of gases liberated by passing 965 C of electricity =1.5×9652×96500mol = 0.0075 mol and value of gases liberated =0.0075×22400,mL=168,mL



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