Chemical Thermodynamics Question 406

Question: In an irreversible process taking place at constant T and P and in which only pressure-volume work is being done, the change in Gibbs free energy (dG) and change in entropy (dS), satisfy the criteria

Options:

A) (ΔS)V,E>0,(ΔG)T,P<0

B) (ΔS)V,E=0,(ΔG)T,P=0

C) (ΔS)V,E=0,(ΔG)T,P>0

D) (ΔS)V,E<0,(ΔG)T,P<0

Show Answer

Answer:

Correct Answer: A

Solution:

  • For spontaneous reaction, dS>0 and ΔG and ΔG should be negative i.e. < 0.


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