Chemical Thermodynamics Question 335

Question: One mole of a non-ideal gas undergoes a change of state (2.0 atm, 3.0 L, 95 K) (4.0 atm, 5.0 L, 245 K) with a change in internal energy, ΔU=30.0L atm. The change in enthalpy ΔH of the process in L atm is.

Options:

A) 40.0

B) 42.3

C) 44.0

D) Not defined because pressure is not constant

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Answer:

Correct Answer: C

Solution:

ΔH=H2H1=(E2+P2V2)(E1+P1V1)

=(E2E1)+(P2V2P1V1)

=30+(4×52×3)=44L atm



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