Shortcut Methods

JEE Main and Advanced:

Shortcut Methods and Tricks:

  1. Periodic Trends:
  • Electronegativity: Increases across a period and decreases down a group.
  • Ionization Energy: Increases across a period and decreases down a group.
  • Atomic Radii: Increases down a group and decreases across a period.
  1. Types of Bonds:
  • Ionic Bonds: Large electronegativity difference (≥1.7).
  • Polar Covalent Bonds: Moderate electronegativity difference (0.4-1.7).
  • Nonpolar Covalent Bonds: Small electronegativity difference (≤0.4).
  1. Bond Formation:
  • Bonds form when atoms achieve a lower potential energy state by sharing or transferring electrons.
  • The number of bonds formed is determined by the valence electrons of the atoms involved.
  1. Electronegativity Difference:
  • The greater the electronegativity difference, the more polar the covalent bond.
  1. Bond Enthalpies:
  • Stronger bonds have higher bond enthalpies.
  • Factors influencing bond strength: bond order, atomic sizes, and presence of multiple bonds.
  1. Coordinate Covalent Bonds:
  • One atom provides both electrons for the bond.
  • Common in complexes and ligands.
  1. Lewis Dot Structures:
  • Represent molecules and ions by showing the arrangement of valence electrons and the formation of bonds.
  • Follow the octet rule and minimize formal charges.

CBSE Board Exams:

Shortcut Methods and Tricks:

  1. Ionic and Covalent Bonds:
  • Ionic bonds have an electronegativity difference ≥1.7.
  • Covalent bonds have an electronegativity difference ≤1.7.
  1. Electron Sharing:
  • Covalent bonds involve the sharing of electron pairs between atoms.
  1. Bond Length and Bond Angle:
  • Bond length: shorter bond corresponds to a stronger bond.
  • Bond angle: determined by the geometry of the molecule (e.g., tetrahedral, octahedral).
  1. Lewis Dot Symbols:
  • Represent the valence electrons of atoms as dots around the atomic symbol.
  1. Polarity of Covalent Bonds:
  • Polar covalent bonds are formed when two atoms have very close and nearly equal electronegativities.
  1. Electronegativity:
  • Electronegativity is the ability of an atom to attract electrons.
  1. Metallic Bonding:
  • Electrons become delocalized and free to move in a metallic lattice, leading to electrical conductivity and thermal conductivity.