Shortcut Methods
JEE Main and Advanced:
Shortcut Methods and Tricks:
- Periodic Trends:
- Electronegativity: Increases across a period and decreases down a group.
- Ionization Energy: Increases across a period and decreases down a group.
- Atomic Radii: Increases down a group and decreases across a period.
- Types of Bonds:
- Ionic Bonds: Large electronegativity difference (≥1.7).
- Polar Covalent Bonds: Moderate electronegativity difference (0.4-1.7).
- Nonpolar Covalent Bonds: Small electronegativity difference (≤0.4).
- Bond Formation:
- Bonds form when atoms achieve a lower potential energy state by sharing or transferring electrons.
- The number of bonds formed is determined by the valence electrons of the atoms involved.
- Electronegativity Difference:
- The greater the electronegativity difference, the more polar the covalent bond.
- Bond Enthalpies:
- Stronger bonds have higher bond enthalpies.
- Factors influencing bond strength: bond order, atomic sizes, and presence of multiple bonds.
- Coordinate Covalent Bonds:
- One atom provides both electrons for the bond.
- Common in complexes and ligands.
- Lewis Dot Structures:
- Represent molecules and ions by showing the arrangement of valence electrons and the formation of bonds.
- Follow the octet rule and minimize formal charges.
CBSE Board Exams:
Shortcut Methods and Tricks:
- Ionic and Covalent Bonds:
- Ionic bonds have an electronegativity difference ≥1.7.
- Covalent bonds have an electronegativity difference ≤1.7.
- Electron Sharing:
- Covalent bonds involve the sharing of electron pairs between atoms.
- Bond Length and Bond Angle:
- Bond length: shorter bond corresponds to a stronger bond.
- Bond angle: determined by the geometry of the molecule (e.g., tetrahedral, octahedral).
- Lewis Dot Symbols:
- Represent the valence electrons of atoms as dots around the atomic symbol.
- Polarity of Covalent Bonds:
- Polar covalent bonds are formed when two atoms have very close and nearly equal electronegativities.
- Electronegativity:
- Electronegativity is the ability of an atom to attract electrons.
- Metallic Bonding:
- Electrons become delocalized and free to move in a metallic lattice, leading to electrical conductivity and thermal conductivity.