Question: The equilibrium concentrations of the species in the reaction A+BC+D are 2,3,10 and 6 mol L1, respectively at 300 K.ΔG0 for the reaction is (R=2cal/molK)

A) 137.26cal

B) 1381.80cal

C) 13.73cal

D) 1372.60cal

Answer: 1381.80cal

Solution:

A+BC+D [A]=2 mol L1 [B]=3 mol L1 [C]=10 mol L1 [D]=6 mol L1 ΔG0=2.303RTlogKeq =2.303RTlog[C][D][A][B] =2.303×2×300×log10×62×3 =2.303×2×300×log10 =1381.8cal