NEET Solved Paper 2019 Question 35

Question: Which of the following reactions are disproportionation reaction? [NEET 5-5-2019]

(i) $ 2C{u^{+}}\to Cu^{2}+Cu^{0} $

(ii) $ 3Mn{O_4}^{2+}+4{H^{+}}\to 2Mn{O_4}^{-}+MnO _2 $ $ +2H _2O $

(iii) $ 2KMnO _4\xrightarrow{\Delta }K _2MnO _4+MnO _2 $ $ +O _2 $

(iv) $ 2MnO_4^{-}+3M{n^{2+}}+2H _2O\to 5MnO _2 $ $ +4{H^{\oplus }} $

Select the correct option from the following:

Options:

A) (i), (iii) and (iv)

B) (i) and (iv) only

C) (i) and (ii) only

D) (i), (ii) and (iii)

Show Answer

Answer:

Correct Answer: B

Solution:

$ {{\overset{+7}{\mathop{KMnO}}}_4}\to K _2{{\overset{+6}{\mathop{MnO}}} _4}+{{\overset{+4}{\mathop{MnO}}}_4} $

$ C{u^{+1}}\to C{u^{+2}}+Cu^{0} $ Disproportionate $ Rx^{n} $

$ \overset{+6}{\mathop{Mn}},O_4^{-2}\to \overset{+7}{\mathop{Mn}},{O_4}^{-}+4\overset{+4}{\mathop{Mn}},O _2 $ (i), (ii) only