Neet Solved Paper 2013 Question 38

Question: Some meta-directing substituents in aromatic substitution are given. Which one is most deactivating?

Options:

A) $ -C\equiv N $

B) $ -S{O_3}H $

C) $ -COOH $

D) $ -N{O_2} $

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Answer:

Correct Answer: D

Solution:

The deactivating tendency of given groups follows the order

$ -NO _2>-SO _3H>-C\equiv N>-\overset{\begin{smallmatrix} O \\ || \end{smallmatrix}}{\mathop{C}},-OH $

Thus, ? $ NO _2 $ is the most deactivating group.