Atoms - Result Question 12

13. Given the value of Rydberg constant is $10^{7} m^{-1}$, the wave number of the last line of the Balmer series in hydrogen spectrum will be : [2016]

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======= ####13. Given the value of Rydberg constant is $10^{7} m^{-1}$, the wave number of the last line of the Balmer series in hydrogen spectrum will be : [2016]

c3eec34ec6b1fad69db54a20ad4b2dca40c2aa54 (a) $0.025 \times 10^{4} m^{-1}$

(b) $0.5 \times 10^{7} m^{-1}$

(c) $0.25 \times 10^{7} m^{-1}$

(d) $2.5 \times 10^{7} m^{-1}$

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Answer:

Correct Answer: 13. (c)

Solution:

  1. (c) According to Bohr’s theory, the wave number of the last line of the Balmer series in hydrogen spectrum,

For hydrogen atom $Z=1$

$\frac{1}{\lambda}=RZ^{2}(\frac{1}{n_2^{2}}-\frac{1}{n_1^{2}})$

$=10^{7} \times 1^{2}(\frac{1}{2^{2}}-\frac{1}{\infty^{2}})$

$\Rightarrow$ wave number $\frac{1}{\lambda}=0.25 \times 10^{7} m^{-1}$

Last line of the series is called series limit. For this line wavelength is minimum $(\lambda _{\min })$.

For minimum wavelength, $n_2=\infty, n_1=n$

So, wavelength $\lambda _{\min }=\frac{n^{2}}{R}$



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