The Solid State - Result Question 34

####34. Formula of nickel oxide with metal deficiency defect in its crystal is Ni0.98O. The crystal contains Ni2+ and Ni3+ ions. The fraction of nickel existing as Ni2+ ions in the crystal is

(a) 0.31

(b) 0.96

(c) 0.04

(d) 0.50

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Solution:

  1. (b) Ni0.98O=(Ni2+)x(Ni3+)0.98x(O2)1

Net charge =0

[x×2]+[(0.98x)×3]+[2×1]=0x=0.94

Fraction of nickel existing as

Ni2+=0.940.98=0.9590.96



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