The Solid State - Result Question 32

####32. In the fluorite structure, the coordination number of $Ca^{2+}$ ion is :

(a) 4

(b) 6

(c) 8

(d) 3

[1993]

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Solution:

  1. (c) In fluorite structure, each $F^{-}$ion is surrounded by four $Ca^{2+}$ ions whereas, each $Ca^{2+}$ is surrounded by eight $F^{-}$ions, giving a body centred cubic arrangement. Thus the co-ordination number of $Ca^{2+}=8$.


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