The sBlock Elements - Result Question 7

####7. The sequence of ionic mobility in aqueous solution is :

[2008]

(a) K+>Na+>Rb+>Cs+

(b) Cs+>Rb+>K+>Na+

(c) Rb+>K+>Cs+>Na+

(d) Na+>K+>Rb+>Cs+

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Solution:

  1. (b) Smaller the ion more is its ionic mobility in aqueous solution. Ionic radii of the given alkali metals is in the order Na+<K+<Rb+<Cs+and thus expected ionic mobility will be in the same order Cs+<Rb+<K+<Na+. However due to high degree of solvation (or hydration) and because of lower size or high charge density, the hydrated ion size follows the same order Cs+<Rb+<K+<Na+and thus conductivity order is Cs+>Rb+>K+>Na+.

(d) The stability of alkali metal hydrides decreases from Li to Cs. It is due to the fact that MH bonds becomes weaker with increase in size of alkali metals as we move down the group from Li to Cs. Thus the order of stability of hydrides is

LiH>NaH>KH>RbH>CsH



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