The sBlock Elements - Result Question 4

####4. Which one of the alkali metals, forms only, the normal oxide, M2O on heating in air?

(a) Rb

(b) K

(c) Li

(d) Na

[2012]

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Solution:

  1. (c) All the alkali metals when heated with oxygen form different types of oxides for example lithium forms lithium oxide (Li2O), sodium forms sodium peroxide (Na2O2), while K,Rb and Cs form their respective superoxides.

Li+being smallest, combines with small anion O2 to form stable Li2O.

The Na+being relatively larger than Li+and weaker positive field than Li+, combines with O22 (peroxide ion) to form Na2,O2K+,Rb+and Cs+ being relative larger than Na+and with weaker positive field than Na+combines with O2 (superoxide ion) to for KO2,RbO2 and CsO2 respectively.



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