The P Block Elements - Result Question 47

####48. Which of the following is the most basic oxide?

(a) $Sb_2 O_3$

(c) $SeO_2$

(b) $Bi_2 O_3$

(d) $Al_2 O_3$

[2006]

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Solution:

  1. (b) More the oxidation state of the central atom (metal), more is its acidity. Hence, $SeO_2$ (O. S. of $Se=+4)$ is acidic. Further for a given O.S., the basic character of the oxides increases with the increasing size of the central atom. Thus $Al_2 O_3$ and $Sb_2 O_3$ are amphoteric and $Bi_2 O_3$ is basic.


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