The dand fblock elements - Result Question 79

####79. The correct order of ionic radii of $Y^{3+}, La^{3+}, Eu^{3+}$ and $Lu^{3+}$ is

[2003]

(a) $La^{3+}<Eu^{3+}<Lu^{3+}<Y^{3+}$

(b) $Y^{3+}<La^{3+}<Eu^{3+}<Lu^{3+}$

(c) $Y^{3+}<Lu^{3+}<Eu^{3+}<La^{3+}$

(d) $Lu^{3+}<Eu^{3+}<La^{3+}<Y^{3+}$

(Atomic nos. $Y=39, La=57, Eu=63, Lu=71$ )

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Solution:

  1. (c) In lanthanide series there is a regular decrease in the atomic as well as ionic radii of trivalent ions $(M^{3+})$ as the atomic number increases. Although the atomic radii do show some irregularities but ionic radii decreases from $La(103 pm)$ to $Lu(86 pm)$.


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