The dand fblock elements - Result Question 59

####59. Cuprous compounds such as $CuCl, CuCN$ and $CuSCN$ are the only salts stable in water due to

[1996]

(a) high hydration energy of $Cu^{+}$ions

(b) their inherent tendency to not disproportionate

(c) diamagnetic nature

(d) insolubility in water

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Solution:

  1. (d) Although $Cu^{2+}$ state is more stable than $Cu^{+}$, but $Cu^{+}$ion can be stabilized by formation of insoluble substances such as $CuCl, CuCN$ and $CuSCN$. $Cu^{2+}$ is more stable than $Cu^{+}$ because of its high hydration energy.


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