The dand fblock elements - Result Question 48

####48. Which of the statements is not true? [2012]

(a) On passing H2S through acidified K2Cr2O7 solution, a milky colour is observed.

(b) Na2Cr2O7 is preferred over K2Cr2O7 in volumetric analysis.

(c) K2Cr2O7 solution in acidic medium is orange.

(d) K2Cr2O7 solution becomes yellow on increasing the pH beyond 7 .

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Solution:

(b) Na2Cr2O7 is hygroscopic in nature and therefore accurate weighing is not possible in normal atmospheric conditions. A hygroscopic substance absorbs moisture from atmosphere and this could lead to inaccuracies in weight.



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