Structure of Atom - Result Question 16

####16. In hydrogen atom, energy of first excited state is $-3.4 eV$. Find out $K E$ of the same orbit of Hydrogen atom

[2002]

(a) $+3.4 eV$

(b) $+6.8 eV$

(c) $-13.6 eV$

(d) $+13.6 eV$

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Solution:

  1. (a) Suppose the nucleus of hydrogen atom have charge of one proton $+e$. The electron revolves in an orbit of radius $r$ around it. Therefore the centripetal force is supplied by electrostatic force of attraction between the electron and nucleus i.e.

$\frac{m v^{2}}{r}=\frac{Z e^{2}}{r^{2}}$

or $m v^{2}=\frac{Z e^{2}}{r}$

or $\frac{1}{2} m v^{2}=\frac{1}{2} \frac{Z e^{2}}{r}=K . E$

now total energy $(E_n)=K . E+$ P.E

in first excited state

$E=\frac{1}{2} m v^{2}+[-\frac{Z e^{2}}{r}]$

$=+\frac{1}{2} \frac{Z e^{2}}{r}-\frac{Z e^{2}}{r}$

$-3.4 eV=-\frac{1}{2} \frac{Z e^{2}}{r}$

$\therefore K . E=\frac{1}{2} \frac{Z e^{2}}{r}=+3.4 eV$

For Bohr orbit, kinetic energy $=-$ Total energy and Potential energy $=2 \times$ Total energy.



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