States of Matter - Result Question 13

####13. $500 mL$ of nitrogen at $27^{\circ} C$ is cooled to $-5^{\circ} C$ at the same pressure. The new volume becomes

(a) $326.32 mL$

(b) $446.66 mL$

(c) $546.32 mL$

(d) $771.56 mL$

[1995]

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Solution:

  1. (b) Given initial volume $(V_1)=500 mL$; Initial temperature $(T_1)=27^{\circ} C=300 K$ and final temperature $(T_2)=-5^{\circ} C=268 K$.

From Charle’s law :

$\frac{V_1}{T_1}=\frac{V_2}{T_2}$ or $\frac{500}{300}=\frac{V_2}{268}$

Where $V_2=$ New volume of gas

$V_2=\frac{500}{300} \times 268=446.66 ml$.



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