Some Basic Concepts of Chemistry - Result Question 37

####37. An organic compound containing $C, H$ and $N$ gave the following analysis :

$C=40 % ; H=13.33 % ; N=46.67 %$

Its empirical formula would be

[1998]

(a) $C_2 H_7 N_2$

(c) $CH_4 N$

(b) $CH_5 N$

(d) $C_2 H_7 N$

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Solution:

  1. (c) As the sum of the percentage of $C, H & N$ is 100 . Thus, it does not contains $O$ atom.

Table for empirical formula

\begin{tabular}{lllll} \hline Element % & \begin{tabular}{l} At. \\ wt. \end{tabular} & \begin{tabular}{l} Relative \\ Number \end{tabular} & Ratio \\ \hline $C$ & 40.00 & 12 & $\frac{40}{12}=3.33$ & $\frac{3.33}{3.33}=1$ \\ \hline $H$ & 13.33 & 1 & $\frac{13.33}{1}=13.33$ & $\frac{13.33}{3.33}=4$ \\ \hline $N$ & 46.67 & 14 & $\frac{46.67}{14}=3.33$ & $\frac{3.33}{3.33}=1$ \\ \hline \end{tabular}

Hence, empirical formula $=CH_4 N$



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