Some Basic Concepts of Chemistry - Result Question 3

####6. If Avogadro number NA, is changed from 6.022×1023mol1 to 6.022×1020mol1 this would change :

[2015 RS]

(a) the definition of mass in units of grams

(b) the mass of one mole of carbon

(c) the ratio of chemical species to each other in a balanced equation.

(d) the ratio of elements to each other in a compound

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Solution:

(b) If 6.022×1023 changes to 6.022×1020/mol then this would change mass of one mole of carbon.

Mass of 12C carbon is used to define the atomic mass unit. In this system, 12C is assigned a mass of exactly 12 a.m.u.

Earlier one mole was defined as the amount of substance that contains as many particles as there are atoms in exactly 12g of the 12C isotope. From November 2018, one mole is defined as exactly 6.02214076×1023 constitutive particles, which may be atoms, molecules, ions or electrons.

Hence, if we change the value of NA from 6.022× 1023mol1 to 6.022×1020mol1 then mass of one mole of carbon will also change.

The definition of mass is independent of Avogadro number NA.

(3) Molecules of water = mole ×NA=103NA



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