Organic Chemistry Some Basic Principles and Techniques - Result Question 47

####53. Arrange the following in increasing order of stability

[NEET Kar. 2013]

(A) $(CH_3)_2 \stackrel{\oplus}{C}-CH_2 CH_3$

(B) $(CH_3)_3-\stackrel{\oplus}{C}$

(C) $(CH_3)_2-\stackrel{\oplus}{C} H$

(D) $CH_3-\stackrel{\oplus}{C} H_2$

(E) $CH_3$

(a) E $<$ D $<$ C $<$ B $<$ A

(b) E $<$ D $<$ C $<$ A $<$ B

(c) D $<$ E $<$ C $<$ A $<$ B

(d) A $<$ E $<$ D $<$ C $<$ B

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Solution:

  1. (b) Greater the number of $e^{-}$donating alkyl groups ( + I effect), greater will be the stability of carbocations.


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