Hydrocarbons - Result Question 86

####89. The most reactive compound for electrophilic nitration is

[1992]

(a) Benzene

(b) Nitrobenzene

(c) Benzoic acid

(d) Toluene.

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Solution:

  1. (d) Due to + I-effect of the $CH_3$-group, toluene has much higher electron density in the ring than benzene, Nitrobenzene and benzoic acid.

Nitro and carboxylic group show- I-effect and hence deactivate the ring towards electrophillic substutution.

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