Hydrocarbons - Result Question 77

####80. The correct order of reactivity towards the electrophilic substitution of the compounds aniline (I), benzene (II) and nitrobenzene (III) is

[2003]

(a) I > II > III

(b) III > II > I

(c) II > III > I

(d) I < II > III

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Solution:

  1. (a) Amino group is ring activating while nitro group is deactivating. Hence, correct order is aniline > benzene > nitrobenzene.

I > II > IIINc1ccccc1

I

IIO=N+c1ccccc1

III NO2 is an electron attracting group hence decrease the electron density on ring, whereas NH2 group is electron releasing group hence increase electron density on ring. Benzene is also erich due to delocalization of electrons.



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