Hydrocarbons - Result Question 75

####77. The order of decreasing reactivity towards an electrophilic reagent, for the following would be

[2007] (i) benzene (ii) toluene (iii) chlorobenzene (iv) phenol

(a) (ii) > (iv) > (i) > (iii) (b) (iv) > (iii) > (ii) > (i)

(c) (iv) > (ii) > (i) > (iii) (d) (i) > (ii) > (iii) > (iv)

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Solution:

  1. (c) Electrophiles have high affinity for electrons. They attack at the site where electron-density is highest. Electron donating groups increases the electron density. The electron donating tendency decreases in the order :

OH>CH3>H>Cl

Therefore, the correct order of reactivity towards electrophile is

C6H5OH>C6H5CH3>C6H6>C6H5Cl

78 .

(c)



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