Hydrocarbons - Result Question 67

####69. Some meta-directing substituents in aromatic substitution are given. Which one is most deactivating?

(a) $-SO_3 H$

(b) $-COOH$

(c) $-NO_2$

(d) $-C \equiv N$

[NEET 2013]

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Solution:

  1. (c) Decreasing order of deactivating effect of the given $m$-directing group is

$>NO_2>-CN>-SO_3 H>-COOH$

$-NO_2$ group is most deactivating group due to strong $-E,-I$ and $-M$ effects.



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