Hydrocarbons - Result Question 6

####6. In the following the most stable conformation of $n$-butane is:

[2010] (a)CC1CCC2CC3CCCC1C32CCC1CCCCC1(C)C

(d)

(b)

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Solution:

  1. (b) The bulky methyl groups are maximum away from each other.

Eclipsed conformation is the highest energy conformation because of unfavorable interactions between the electrons in the front and back $C-H$ bonds. The energy of eclipsed conformation is approx. $3 kcal / mol$ higher than stagged conformation.



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