Hydrocarbons - Result Question 59

####61. Reduction of 2-butyne with sodium in liquid ammonia gives predominantly

[1993]

(a) cis-2-butene

(b) No reaction

(c) trans-2-butene

(d) n-butane.

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Solution:

  1. (c) Reduction of alkynes with $Na /$ liq. $NH_3$ gives trans-alkenes. This reaction is called Birch reduction

$ CH_3-C \equiv C-CH_3+H_2 $



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