Hydrocarbons - Result Question 56

####58. Predict the product $C$ obtained in the following reaction of butyne-1.

[2007]

$CH_3 CH_2-C \equiv CH+HCl \longrightarrow B \xrightarrow{HI} C$

(a)CCCCI

(b)CCC(I)CCl

(c)CCC(C)(Cl)I

(d)CC(Cl)CCI

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Solution:

(c) $CH_3-CH_2-C \equiv CH+HCl$C=C(Cl)CC

According to Markownikoff’s rule which states that when an unsymmetrical alkene undergo hydrohalogenation, the negative part goes to the $C$-atom which contain lesser no. of $H$-atom.



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