SATHEE: Hydrocarbons - Result Question 33

Hydrocarbons - Result Question 33

####35. Which of the following reagents convert propene to 1-propanol?

[2000]

(a) $H_{2} O, H_{2} S O_{4}$

(b) aqueous $K O H$

(c) $M g S O_{4}, N a B H_{4} / H_{2} O$

(d) $B_{2} H_{6}, H_{2} O_{2}, O H^{-}$

Show Answer

Solution:

(d) We know that

$\begin{aligned} \underset{Propene}{6 C H_{3} - C H} = C H_{2} \underset{ether, 0^{\circ} C}{B_{2} H_{6}} \\ 2 (C H_{3} C H_{2} C H_{2})_{3} B \to_{\begin{array}{c} O H^{-} \end{array}}^{H_{2} O_{2}} \\ 6 C H_{3} C H_{2} C H_{2} O H + 2 H_{3} B O_{3} \end{aligned}$

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