Haloalkanes and Haloarenes - Result Question 5

####5. Which of the following compounds will undergo racemisation when solution of $KOH$ hydrolyses?

[2014]

(i)ClCc1ccccc1

(ii)CCCCl $CH_3$

(iii)CCCCl

(iv)CCC(C)Cl

(a) (i) and (ii)

(b) (ii) and (iv)

(c) (iii) and (iv)

(d) (i) and (iv)

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Solution:

  1. (N) The compound in option (iv) will undergo $S_N 1$ reaction with $KOH$ solution. Hence, only this compound will undergo partial racemisation. Compounds given in other options are not chiral.


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