Haloalkanes and Haloarenes - Result Question 35

####35. When chlorine is passed through propene at $400^{\circ} C$, which of the following is formed? [1993]

(a) PVC

(b) Allyl chloride

(c) Alkyl chloride

(d) 1,2-Dichloroethane

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Solution:

  1. (b) At high temp. i.e., $400^{\circ} C$ substitution occurs in preference to addition.

$ CH_3 CH=CH_2 \xrightarrow[-HCl]{Cl_2, 400^{\circ} C} $

$ ClCH_2 CH=CH_2 $



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