Haloalkanes and Haloarenes - Result Question 35

####35. When chlorine is passed through propene at 400∘C, which of the following is formed? [1993]

(a) PVC

(b) Allyl chloride

(c) Alkyl chloride

(d) 1,2-Dichloroethane

Show Answer

Solution:

  1. (b) At high temp. i.e., 400∘C substitution occurs in preference to addition.

CH3CH=CH2→−HClCl2,400∘C

ClCH2CH=CH2

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