Haloalkanes and Haloarenes - Result Question 12

####12. If there is no rotation of plane polarised light by a compound in a specific solvent, though to be chiral, it may mean that

[2007]

(a) the compound is certainly meso

(b) there is no compound in the solvent

(c) the compound may be a racemic mixture

(d) the compound is certainly achiral.

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Solution:

  1. (a) Compounds which do not show optical activity inspite of the presence of chiral carbon atoms are called meso-compounds.

The absence of optical activity in these compound is due to the presence of a plane of symmetry in their molecules. e.g. meso-tartaric acid is optically inactive.



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