Equilibrium - Result Question 9

####10. If the concentration of OHions in the reaction Fe(OH)3(s)Fe3+(aq)+3OH(aq) is decreased by 14 times, then equilibrium concentration of Fe3+ will increase by : [2008]

(a) 8 times

(b) 16 times

(c) 64 times

(d) 4 times

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Solution:

  1. (c) For this reaction Keq.  is given by

K=[Fe3+][OH]3[Fe(OH)3]

.=(Fe3+)(OH)3[ solid ]=1].

If (OH)is decreased by 14 times then for given reaction, equilibrium constant to remain constant, we have to increase the concentration of [Fe3+] by a factor of 43 i.e. 4×4×4=64. Thus, option (c) is correct answer.

To maintain the equilibrium constant if concentration of one of the product decreases by 1n times then the concentration of another product is increased by the factor of (n)x, where x is the stoichiometric coeficient.



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