Equilibrium - Result Question 81

####85. If pH of a saturated solution of Ba(OH)2 is 12 , the value of its K(sp) is :

[2010]

(a) 4.00×106M3

(b) 4.00×107M3

(c) 5.00×106M3

(d) 5.00×107M3

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Solution:

(d) Ba(OH)2(s)Ba2+(aq)+2OH(aq) pH=12 or pOH=2

[OH]=102M

Ba(OH)2Ba2++2OH

0.5×102102

[. Concentration of Ba2+ is half of .OH]

Ksp=[Ba2+][OH]2=[0.5×102][1×102]2=0.5×106=5×107M3



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