SATHEE: Equilibrium - Result Question 7

Equilibrium - Result Question 7

####8. In which of the following equilibrium $K_{c}$ and $K_{p}$ are not equal?

[2010]

(a) $2 N O (g) \to N_{2} (g) + O_{2} (g)$

(b) $S O_{2} (g) + N O_{2} (g) \to S O_{3} (g) + N O (g)$

(d) $2 C (s) + O_{2} (g) \to 2 C O_{2} (g)$

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Solution:

(d) $2 C ($ s $) + O_{2} (g) \to 2 C O_{2} (g)$

$Δ n = 2 - 1 = + 1$

$∴ K_{c}$ and $K_{p}$ are not equal.

If $Δ n = 0$ , then $(R T)^{Δ n} = 1$

$\Rightarrow K_{c} = K_{p}$

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Equilibrium - Result Question 7

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