Equilibrium - Result Question 31

####33. Standard Gibb’s free energy change for isomerization reaction

[1995]

cis- 2 - pentene $\rightarrow$ trans-2-pentene

is $-3.67 kJ / mol$ at $400 K$. If more trans-2-pentene is added to the reaction vessel, then

(a) more cis-2-pentene is formed

(b) equilibrium remains unaffected

(c) additional trans-2-pentene is formed

(d) equilibrium is shifted in forward direction

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Solution:

  1. (a) If more trans-2-pentene is added, then its concentration in right hand side will increase. But in order to maintain the $K$ constant, concentration of cis-2-pentene will also increase. Therefore more cis-2-pentene will be formed.


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