Equilibrium - Result Question 20

####21. The rate constant for forward and backward reaction of hydrolysis of ester are $1.1 \times 10^{-2}$ and $1.5 \times 10^{-3}$ per minute respectively. Equilibrium constant for the reaction

[1995]

$CH_3 COOC_2 H_5+H^{+} \rightarrow$

$CH_3 COOH+C_2 H_5 OH$ is

(a) 4.33

(b) 5.33

(c) 6.33

(d) 7.33

Topic 2: Relation between $K, Q$ and $G$ and Factors Effecting Equilibrium

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Solution:

  1. (d) Rate constant of forward reaction $(K_f)$ $=1.1 \times 10^{-2}$ and rate constant of backward reaction $(K_b)=1.5 \times 10^{-3}$ per minute. Equilibrium constant $(K_c)$

$=\frac{K_f}{K_b}=\frac{1.1 \times 10^{-2}}{1.5 \times 10^{-3}}=7.33$



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