Equilibrium - Result Question 1

####1. The equilibrium constant of the following are :

N2+3H22NH3K1N2+O22NOK2H2+12O2H2OK3

The equilibrium constant (K) of the reaction :

2NH3+52O2K2NO+3H2O, will be;

(a) K2K33/K1

(b) K2K3/K1

(c) K23K3/K1

(d) K1K33/K2

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Solution:

  1. (a)

(i) N2+3H22NH3;K1=[NH3]2[N2][H2]3

(ii) N2+O22NO;K2=[NO]2[N2][O2]

(iii) H2+12O2H2O;K3=[H2O][H2][O2]1/2

Applying (II +3×IIII) we will get

2NH3+52O2K2NO+3H2O;

K=[NO]2[N2][O2]×[H2O]3[H2]3×[O2]3/2/[NH3]2[N2][H2]3

K=K2×K33/K1



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