Electrochemistry - Result Question 46

####48. The standard e.m.f. of a galvanic cell involving cell reaction with n=2 is found to be 0.295V at 25C. The equilibrium constant of the reaction would be

(Given F=96500Cmol1;R=8.314JK1mol1 )

(a) 2.0×1011

(b) 4.0×1012

(c) 1.0×102

(d) 1.0×1010

[2004]

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Solution:

(d) E=0.0591nlog10K

Here, n=2,E=0.295

log10K=2×0.2950.0591=10 or K=1×1010



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