Electrochemistry - Result Question 28

####30. For the cell reaction

[2019]

$2 Fe^{3+}(aq)+2 I^{-}(aq) \to 2 Fe^{2+}(aq)+I_2(aq)$

$0.24 V$ at $298 K$. The standard Gibbs energy ( $\Delta$, $G^{\circ}$ ) of the cell reaction is:

[Given that Faraday constant $F=96500 C mol^{-1}$ ]

(a) $-46.32 kJ mol^{-1}$

(b) $-23.16 kJ mol^{-1}$

(c) $46.32 kJ mol^{-1}$

(d) $23.16 kJ mol^{-1}$

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Solution:

  1. (a) $\Delta G=-n F E^{\circ}$

$=-2 \times 96500 \times 0.24=-46320 J / mol$

$=-46.32 kJ / mol$



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