Electrochemistry - Result Question 26

####28. On electrolysis of dilute sulphuric acid using platinum electrodes, the product obtained at the anode will be

(a) hydrogen

(b) oxygen

(c) hydrogen sulphide

(d) sulphur dioxide.

[1992]

Topic 3: Cells and Electrode Potential, Nernst Equation

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Solution:

  1. (b) During electrolysis of sulphuric acid, the following processes are possible at cathode:

2H2O(l)O2(g)+4H+(aq)+4e,

E=+1.23V 2SO42(aq)S2O82(aq)+2e,E=+1.96V

For dilute sulphuric acid, first reaction is preferred but for concentrated acid, second reaction is preferred.



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