Electrochemistry - Result Question 13

####14. If 0.01M solution of an electrolyte has a resistance of 40ohms in a cell having a cell constant of 0.4cm1, then its molar conductance in ohm 1cm2mol1 is

(a) 102

(b) 104

(c) 10

(d) 103

[1997]

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Solution:

  1. (d) Given molarity =0.01M

Resistance =40 ohm;

Cell constant 1A=0.4cm1

Specific conductivity ( κ )

= cell constant  resistance =0.440=0.01ohm1cm1

Molar conductance (m)=1000κ Molarity 

=1000×.01.01=103ohm1cm2mol1



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