Electrochemistry - Result Question 12

####13. Equivalent conductances of NaCl,HCl and CH3COONa at infinite dilution are 126.45,426.16 and 91ohm1cm2 respectively. The equivalent conductance of CH3COOH at infinite dilution would be

[1997]

(a) 101.38ohm1cm2

(b) 253.62ohm1cm2

(c) 390.71ohm1cm2

(d) 678.90ohm1cm2

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Solution:

  1. (c) By Kohlraush’s law, eqNaCl=126.45

λNa++λCl=126.45

λH++λCl=426.16

λCH3OO+λNa+=91

on adding (2) and (3) then subtract (1) from it

λCH3COO+λH+=517.16126.45

\graveU(CH3COOH)=390.71ohm1cm2



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